화학공학소재연구정보센터
Fuel Processing Technology, Vol.140, 57-66, 2015
The effect of hydrothermal treatment on attrition during the fluidized bed combustion of paper sludge
A combination of experimental techniques was employed to test primary fragmentation and char particle attrition by abrasion during fluidized bed (FB) combustion of raw paper sludge (Raw-PS), hydrothermally treated paper sludge (HIT-PS), and a subbituminous coal (Sub-C), for comparison. The hydrothermal treatment (HIT) was conducted by a pilot-scale reactor at 197 degrees C (1.9 MPa) for 30 min. The results showed that all three samples extensively underwent primary fragmentation. Char attrition tests under inert conditions showed that Sub-C intensely experienced particle rounding off at the beginning, but after that it became very strong against mechanical abrasive attrition, followed by HTT-PS and Raw-PS, respectively. The oxidative char attrition tests showed that Sub-C exhibited an initial low amount of carbon elutriation rate followed by an attrition enhancement effect at later stages of burn-off, whereas for the Raw-PS and HIT-PS attrition was always lower than under inert conditions due to extensive postcombustion of fines. HTT-PS always produced a lower amount of elutriated carbon than Raw-PS and this indicates better combustion performance as well as lower unburned carbon emission. Finally, the Primary Ash Particle Size Distribution (PAPSD) of the three fuels was determined, showing that the paper sludge would contribute much more than coal to the ash bed inventory in a full-scale FB combustor. (C) 2015 Elsevier B.V. All rights reserved.