Journal of Materials Science, Vol.31, No.16, 4357-4362, 1996
Characteristics of SrTiO3 Thin-Films Deposited Under Various Oxygen Partial Pressures
SrTiO3 thin films were deposited by rf-magnetron sputtering under various sputtering conditions followed by conventional furnace annealing at 600 and 700 degrees C. The amorphous SrTiO3 thin films crystallized into polycrystals at 600 degrees C. The leakage current of the SrTiO3 thin films decreased with increasing oxygen partial pressure in the sputtering gas. On the contrary, the dielectric constant increased with increasing the oxygen content in the sputtering gas. The leakage current and dielectric constant increased with increasing substrate temperature and post-annealing temperature. The ratio of Sr:Ti approached 1:1 with increasing oxygen content in the sputtering gas and substrate temperature during deposition. The oxygen content in the film decreased with increasing the substrate temperature. The capacitance-voltage (C-V) curves showed that the capacitance was nearly independent of the applied voltage. Scanning electron microscopy (SEM) micrographs showed that interdiffusion between the bottom electrode (Pt) and the buffer layer (Ti) occurred during post-annealing, but that the interface between SrTiO3 and Pt was stable.