화학공학소재연구정보센터
Journal of Materials Science, Vol.31, No.18, 4899-4906, 1996
Microstructure, Chemical-Reaction and Mechanical-Properties of TiC/Si3N4 and Tin-Coated TiC/Si3N4 Composites
Silicon nitride containing various com positions of as-received TiC a nd TiN-coated TiC, were hot pressed at 1800 degrees C for 1 h in a nitrogen atmosphere. In TiN-coated TiC/Si3N4 composites, TIC reacted first with the TiN coating to form a titanium carbonitride interlayer at 1450 degrees C, which essentially reduced further reactions between TiC and Si3N4 and enhanced densification. TiN-coated TiC/Si3N4 composites exhibited better densification, hardness, flexural strength a nd fracture toughness than those of as-received TiC/Si3N4. The toughening mechanisms for as-received TiC/Si3N4 and TiN-coated TiC/Si3N4 composite were attributed to crack deflection, load transfer and crack impedence by the compressive thermal residual stress.