The objective of this investigation was to study how the mechanical properties of an optically transparent composite varied with the geometrical arrangement, stacking sequence, of polymethylmethacrylate (PMMA) (designated as P) and composite (designated as C) layers. The multi-layered composites (about 6.63 mm thick) were highly transparent between 22 to 46 degrees C in the visible region. As expected, the sandwich structure, (CCPP)s had the highest Young’s modulus while (PCCP)s and (PPCC)s composites had the highest flexural strength and work of fracture, respectively. The flexural strength of these laminated composites, which contained only 0.8 vol% fibre without any coupling agent, was up to 21% higher than that of pure PMMA. The stress distribution through the thickness at the midpoint of a sample loaded in three-point bending was computed by the finite element method (FEM). The computed stress distribution allowed the expected point of failure to be established. The relationship between the stacking sequence, stress level under a given load, and strength was also investigated. The observed fracture modes were complex and the maximum stress failure criterion did not fit these composites. The fracture was always complex (tensile and shear), starting with tensile failure followed by shear mode (delamination) and another tensile mode. The first crack always commenced at a PMMA layer adjoining the composite layer which contained the highest stress. The optimum stacking sequence when such composites are used as a window is concluded to be (PCCP)s, since this sequence had the highest flexural strength (141 MPa) and a moderate work of fracture (37 kJ m(-2)).