화학공학소재연구정보센터
Applied Chemistry, Vol.2, No.1, 294-297, May, 1998
음이온 교환수지의 확산계수 측정
An evaluation of diffusion coefficient for anion-exchange resin
Mass-transfer coefficient for anion exchange was determined for commercially available strong-base anion exchange resin of Cl- type in use to remove nitrate in water. Experiments were performed over an initial solution concentration range from 5 to 50ppm nitrate and temperature range from 283 to 323K in 2L batch reactor. Effective diffusion coefficient was obtained in the range from 9.67×108 to 1.67×106 cm2/sec for initial concentration change, and from 6.09×10-7 to 3.98×10-6 cm2/sec for reaction temperature change. Activation energy during the diffusion was calculated as 36 kcal/mol.