Natural convection heat transfer was investigated in vertical cavities where either all surfaces were active, or only the vertical surface was active for four different geometries, which were varied by placing a disk at the top and/or bottom of the cavity. A cupric acid copper sulfate electroplating system was employed for mass transfer experiments exploiting the analogy with heat transfer. The Rayleigh number was varied in the range 4.55 x 10(9) <= Ra-Lw <= 3.79 x 10(13). Preliminary tests for a vertical pipe, upward-and downward-facing horizontal disks showed good agreement with existing correlations. The measured Nusselt numbers in the vertical cavities with all surfaces active were always greater than those with only the vertical surface active, which is attributed to greater hydrodynamic interaction of the flows generated by different surfaces. When all surfaces were active, the bottom-closed cavity exhibited the largest heat transfer rates, followed by both-closed, top-closed, and both ends open cavities; this trend was observed with laminar and turbulent flows. With only the vertical surface active, similar trends were observed except that the heat transfer rates were almost identical for both-open and top-closed cavities, which is attributed to the weak influence of the top disk on the heat transfer characteristics. Using these results, empirical correlations were derived for both laminar and turbulent flow conditions. (C) 2015 Elsevier Ltd. All rights reserved.