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Journal of Materials Science, Vol.32, No.2, 549-554, 1997
Double Yield Points in Triblends of LDPE, LLDPE and EPDM
Factors that affect to the proposed mechanisms that produce the double yield phenomenon in semicrystalline polymeric materials were studied. The systems under study were ternary blends of low-density polyethylene (LDPE), linear LDPE (LLDPE) and ethylene propylene diene (EPDM). The influence on the yield mechanisms of the following different factors were analysed : processing conditions, composition, stretching rate, cooling conditions and different types of elastomers. The behaviour of these blends in the region where the double-yield points occur was found to be different for those LDPE-rich blends from those LLDPE-rich ones. These differences are explained in terms of the two mechanisms in the double yield phenomenon; that is, the slip of the crystalline blocks and the shear on the crystalline blocks. The stretching-rate effect is explained in terms of the stress relaxation time. The effects of EPDM content, cooling conditions and type of EPDM are found to be equivalent to a smaller stretching rate.
Keywords:POLYETHYLENE