화학공학소재연구정보센터
Journal of Adhesion Science and Technology, Vol.29, No.13, 1382-1402, 2015
Effects of a sheet metal stamping lubricant on static strength of adhesive-bonded aluminum alloys
Stamping lubricant is often applied to sheet metal surface to improve the formability. In this study, the effect of stamping lubricant on the strength of adhesive-bonded 1.0-mm-thick bare aluminum (Novelis X610-T4PD) and 0.9-mm-thick bare aluminum (Novelis X626-T4P) joints was investigated. It was found that while a proper amount of lubricant (~2.21g/m(2), 1.5 mu L lubricant on the 25 x 25mm coupon) applied on the surface of the substrate had little effect on the joint strength, levels more than 2.21g/m(2) lubricant significantly decreased the joint strength. When the lubricant amount exceeds the adhesive's compatibility with the lubricant, the negative effects of pores from lubricant evaporation during curing on the strength overrides the positive effect of increased adhesion energy. Furthermore, the presence of 2.21g/m(2) lubricant minimized the reduction of the strength of the joints pre-exposed to neutral salt spray (i.e. a concentration of 50 +/- 5g/L sodium chloride solution). Careful analyses of the results indicated that corrosion of aluminum substrate surfaces of the pre-exposed joints led to the degradation in bond adhesion between the adhesive and substrates, and consequently resulted in the decrease of the joint strength. The hydrophobic lubricant protected the aluminum substrate from electrochemical reaction by damage of the bond adhesion between the adhesive and substrates leading to the lubricated joints having better corrosion resistance than the unlubricated joints.