화학공학소재연구정보센터
Journal of Chemical and Engineering Data, Vol.60, No.8, 2420-2425, 2015
Transfer Properties of Glycylglycine from Water to Aqueous NaNO3, NaClO4, and Na2SO4 Solutions
Enthalpies of solution and densities of glycylglycine in aqueous solutions of NaNO3, NaClO4, and Na2SO4 were measured at 298.15 K. Standard transfer enthalpies (Delta H-tr(0)), standard transfer partial molar volume (Delta V-tr(phi)0), and hydration numbers (N-h) have been determined for glycylglycine. All of the Delta H-tr(0) values are negative in the three salt solutions. The relative order of Delta H-tr(0) in the same concentration of 1-1 type salts is NaNO3 > NaClO4. The Delta H-tr(0) in low concentration of Na2SO4 solutions is between the corresponding values in NaNO3 and NaClO4 solutions. With increasing Na2SO4 concentration, the Delta H-tr(0) values exceed that in NaNO3 solutions. The Delta V-tr(phi)0 values are positive and vary in the sequence Na2SO4 > NaNO3 > NaClO4. The results were discussed in terms of various interactions.