Applied Chemistry, Vol.3, No.1, 13-16, April, 1999
폴리이소프로필아크릴아마이드와 폴리에틸렌글리콜계 폴리우레탄으로 구성된 Semi-IPN 수화겔의 제조와 팽윤거동
Preparation and Swelling Behavior of Semi-IPN hydrogels composed by Poly(N-isopropyl acrylamide) and Poly (ethylene glycol)-based urethane
Poly (ethylene glycol)-based urethane (PEG-PU) was introduced as a rubbery material to enhance mechanical properties of thermo-responsive cross-linked poly (N-isopropylacrylamide) (PNiPAAm) hydrogel by IPN formation technique. Semi-IPN hydrogels were synthesized with the ratio of PNiPAAm to PEG-PU (100/0, 95/5, 90/10, and 80/20). The various swelling or/and-deswelling behaviors were examined as a function of temperature. The volume phase transition temperatures (Tp) of semi-IPN hydrogels were little affected by the incorporation of PEG-PU chains in IPN structures. This observation indicates that each network in the swollen IPNs exists independently. The faster swelling-deswelling kinetics of semi-IPN hydrogels was observed via introduction of PEG-PU in IPNs in contrast to the pure PNiPAAm gel. These results were interpreted as a formation of water release channels within the skin layer by the hydrophilic PEG-PU chain.