Developing functional porous materials with highly efficient oil-water separation ability are of great importance due to the global scale of severe water pollution arising from oil spillage and chemical leakage. A solution immersion process was used to fabricate polydimethylsiloxane (PDMS)-coated cotton, which exhibited superhydrophobic and superoleophilic properties. The water contact angle of similar to 157 degrees and mass of similar to 1.49 g were retained after 1000 compression cycles, indicating that the PDMS was strongly attached to the cotton fibres. The PDMS-coated cotton absorbed various oils and organic solvents with high selectivity, high absorption capacity (up to 7080 wt.%), and good recyclability (exceeding 500 cycles). Notably, the loading capacity of the PDMS-coated cotton against water exhibited a similar trend to its oil absorption capacity. These findings will further the application of superhydrophobic and superoleophilic porous materials in oil/water separation. (C) 2015 Elsevier B.V. All rights reserved.