Journal of Molecular Catalysis A-Chemical, Vol.403, 64-76, 2015
Surface modification of silica-coated gadolinium oxide nanoparticles with zinc tetracarboxyphenoxy phthalocyanine for the photodegradation of Orange G
Zinc tetracarboxyphenoxy phthalocyanine was covalently linked to Gd2O3 nanoparticles for the photocatalytic degradation of Orange G. Characterization of the composite was carried out Using XRD, TEM, XPS, UV-vis spectroscopy and FT-IR spectroscopy. The composite showed improved photophysical properties over the phthalocyanine alone and the catalyst was found to be reusable. Analyses of the photodegradation rates of the azo dye indicated pseudo first-order kinetics. (C) 2015 Elsevier B.V. All rights reserved.