Journal of Materials Science, Vol.33, No.9, 2283-2297, 1998
Incipient melting of Al5Mg8Si6Cu2 and Al2Cu intermetallics in unmodified and strontium-modified Al-Si-Cu-Mg (319) alloys during solution heat treatment
The present work was performed on seven alloys containing in common Al-6.5 wt%Si-3.5 wt% Cu, with magnesium in the range 0.04-0.45wt%, and strontium in the range 0-300 p.p.m. The alloys were cast in the form of tensile test bars, solution heat treated in the temperature range 480-540 degrees C for times up to 24 h. Two types of solution heat treatment were applied: (i) single-stage, where the test bars were solution treated at a certain temperature for 12 h prior to quenching in hot water (60 degrees C); (ii) two-stage, where the test bars were solution treated for 12 h/510 degrees C + 12 h/T degrees C (T = 510, 520, 530, 540 degrees C), followed by quenching in hot water. In the low-magnesium alloys (i.e. with Mg similar to 0.04 wt%), melting of the Al2Cu phase commenced at 540 degrees C. Increasing the magnesium content to similar to 0.5 wt% reduced the incipient melting temperature of the Al5Mg8Si6Cu2 phase to 505 degrees C. The mechanism of incipient melting and its effect on the tensile properties have been discussed in detail.
Keywords:PHASE PARTICLES;DISSOLUTION