This work, for the first time, presents sulfur electrodes for lithium/sulfur (Li/S) batteries produced by a newly developed single-step electroforming process, which allows simultaneous sulfur incorporation during electroformation of an electrically conducting electrode. This metal is used as binding matrix for the sulfur particles and thereby makes any binder and conducting carbon additives redundant. Furthermore, it serves by itself as the current collector, so that all functionalities (current collector, binder and electrical conductor towards sulfur) are fulfilled by the electroformed metal, while modified sulfur particles are directly incorporated (composite electroformation). In this way, the sulfur cathode can be produced in a single continuous step in form of a metal foil with adjustable thickness and sulfur loading. The process requires functionalization of sulfur to improve its wettability, incorporation homogeneity and volume which is provided by wrapping sulfur particles with polythiophene. Electroformed copper-sulfur composite foils are chosen as a first proof of the new concept. The achieved battery capacity, cycling stability and coulombic efficiency are presented. It is shown that the electroformed copper-sulfur composite foil operates very well as a battery cathode and a discharge capacity of over 400 mAh g(-1) at a rate of 0.5 C over 100 cycles is preserved. (C) 2015 Elsevier B.V. All rights reserved.