Membrane electrode assembly (MEA), which contains cathode and anode catalytic layer, gas diffusion layers (GDL) and electrolyte membrane, is the key unit of a PEMFC. An attempt to develop MEA for ABPBI membrane based high temperature (HT) PEMFC is conducted in this work by catalyst coating membrane (CCM) method. The structure and performance of the MEA are examined by scanning electron microscopy (SEM), electrochemical impedance spectroscopy (EIS) and I-V curve. Effects of the CCM preparation method, Pt loading and binder type are investigated for the optimization of the single cell performance. Under 160 degrees C and atmospheric pressure, the peak power density of the MEA, with Pt loading of 0.5 mg cm(-2) and 0.3 mg cm(-2) for the cathode and the anode, can reach 277 mW cm(-2), while a current density of 620 A cm(-2) is delivered at the working voltage of 0.4 V. The MEA prepared by CCM method shows good stability operating in a short term durability test: the cell voltage maintained at similar to 0.45 V without obvious drop when operated at a constant current density of 300 mA cm(-2) and 160 degrees C under ambient pressure for 140 h. (c) 2015 Elsevier B.V. All rights reserved.