화학공학소재연구정보센터
Journal of Materials Science, Vol.33, No.22, 5339-5349, 1998
Single crystal fibers of yttria-stabilized cubic zirconia with ternary oxide additions
Single crystal fibers of yttria (Y2O3)-stabilized cubic zirconia (ZrO2) with ternary oxide additions were grown using the laser float zone fiber processing technique. Ternary additions to the ZrO2-Y2O3 binary system were studied aimed at increasing strength while maintaining the high coefficient of thermal expansion of the binary system. Statistical methods aided in identifying the most promising ternary oxide candidate (Ta2O5, Sc2O3, and HfO2) and optimum composition. The yttria range investigated was 14 to 24 mol% and the ternary oxide component ranged from 1 to 5 mol %. Hafnium oxide was the most promising ternary oxide component based on 816 degrees C tensile strength results and ease of fabrication. The optimum com position for development was 81ZrO(2)-14Y(2)O(3)-5HfO(2) based upon the same elevated temperature strength tests. Preliminary results indicate process improvements could improve the fiber performance. We also investigated the effect of crystal orientation on strength. (C) 11998 Kluwer Academic Publishers.