New catalysts of reduced graphene oxide (rGO) with poly aniline (PANI) and cobalt ferrite (CF) have been successfully prepared by simple chemical reduction method. Their electrocatalytic activity for oxygen reduction reaction (ORR) was evaluated. Semi-crystalline nature of CF was analyzed by X-ray diffraction (XRD) study. Surface morphology by HR-SEM showed features of CF particles and PANI film on graphene sheets. FT-IR studies revealed changes in C-N and C=N tretching vibrations of PANI confirming bonding of PANI to graphene sheets. Raman spectrum showed presence of PANI on distorted graphene layers. TG/ DTA revealed thermal stability and extent of loading of CF in corriposite. ORR performance was studied using catalyst modified rotating disc electrode (RDE). A maximum kinetic current density of -3.46 mA cm(-2) at 0.2 V was obtained for CF/PANI/rGO. Tafel slope, onset and half wave potentials for the catalyst were obtained from ORR response. Durability studies showed that synthesized electrocatalyst has better stability and methanol tolerance than commercial Pt/C catalyst. To the best of our knowledge, this is the first study aiming enhancement of ORR activity using PANI and CoFe2O4 on graphene support. A trace amount of Pt in the composite boosted the performance of single PEM fuel cell. (C) 2015 Elsevier B.V. All rights reserved.