화학공학소재연구정보센터
Journal of Supercritical Fluids, Vol.106, 69-75, 2015
Correlation between the elastic modulus and heat transport along the solid phase in highly porous materials: Theoretical approaches and experimental validation using polyurea aerogels
The elastic modulus and solid phase thermal conductivity were experimentally determined for two series of supercritically dried polyurea aerogels. Both sample series cover a density range between 0.03 and 0.3 g/cm(3), respectively, while micro-structural details of the aerogels are completely different for the samples of the two series, thus leading to considerable differences in macroscopic properties, when comparing two samples from the two series at a given density. On the contrary, elastic modulus is found to strongly correlate with the heat transport along the solid phase, irrespective of the sample series considered. The insensitivity of this correlation to micro-structural details can be explained with theoretical approaches that are used to describe the macroscopic properties of porous materials. However, also possibilities for a structural decoupling of the elastic modulus and the heat transport along the solid phase could be identified that may open new approaches for technical applications. (C) 2015 Elsevier B.V. All rights reserved.