The intelligent humidity control materials were synthesized using fumed silica and quaternary alkylammonium surfactant (decyl-, dodecyl-, tetradecyl- and hexadecyl-trimethylammonium chlorides) as a liquid-crystal template under hydrothermal conditions. X-ray diffraction and transmission electron micrographs indicate that a homogeneous hexagonal structure of SiO2 was formed for those products. The mesostructured products had high B.E.T. surface areas between 960 and 1300 m(2)/g, with uniform mesopore diameters of 2-4 nm. These physical quantities were controlled by varying the size of the organic template. Water vapor adsorption isotherms for these materials possess a sharp increase in adsorption when the relative water vapor pressure is at 40-60%. Over th is range of pressures, the maximum a mount of adsorbed water content is between 40 and 90%. These silicates have the potential to be effectively used as humidity control elements in construction materials.