Herein we report the characterization of localized corrosion of AZ31B magnesium alloy electrochemically coated with poly(3,4-ethylenedioxythiophene) (PEDOT) from ionic liquid electrolyte. Several scanning probe techniques including high resolution electron microscopy, SVET, SECM amperometric detection of H-2 fluxes, potentiometric SECM detection of local pH and localized potentiodyanmic measurements were used to evaluate the microstructure of the coating and its corrosion protectiveness. In order to examine long-term durability of corrosion protection due to the PEDOT coating, these measurements were performed after different immersion times. It was observed that PEDOT coating appears to lose its protective ability after localized coverage of corrosion products. The results of this study provide important information considering the interest in this coating for use in biomedical implants and prior indications of beneficial passivation. (c) The Author(s) 2015. Published by ECS. All rights reserved.