화학공학소재연구정보센터
Materials Research Bulletin, Vol.66, 231-238, 2015
Magnetic, electrical and structural properties of the Re-doped ruthenocuprate Ru1-xRexSr2GdCu2Oy
Despite the discovery of new superconductors classes, high-Tc oxides continue to be a current topic, because of their complex phase diagrams and doping-dependant effects (allowing one to investigate the interaction between orbitals), as well as structural properties such as lattice distortion and charge ordering, among many others. Ruthenocuprates are magnetic superconductors in which the magnetic transition temperature is much higher than the critical superconducting temperature, making them unique compounds. With the aim of investigating the dilution of the magnetic Ru sub-lattice, we proposed the synthesis of the Ru1-xRexSr2GdCu2Oy ruthenocuprate-type family, adapting the known two-step process (double perovskite + CuO) by directly doping the double perovskite, thus obtaining the perovskite compound Sr2GdRu1-xRexOy, which represents a new synthesis process to the best of our knowledge. Our samples were structurally characterized through X-ray diffraction, and the patterns were analysed via Rietveld refinement. A complete magnetic characterization as a function of temperature and applied field, as well as transport measurements were carried out. We discuss our results in the light of the two-lattice model for ruthenocuprates, and a relation between RuO2 (magnetic) and CuO2 (superconductor) sub-lattices can clearly be observed. (C) 2015 Elsevier Ltd. All rights reserved.