화학공학소재연구정보센터
Materials Research Bulletin, Vol.72, 241-244, 2015
Influence of temperature and frequency on ionic conductivity of Li3PO4-Pb-3(PO4)(2)-BiPO4 phosphate glasses
Lithium-Lead-Bismuth phosphates glasses having, a composition 30Li(3)PO(4)-(70-x)Pb-3(PO4)(2)-xBiPO(4) (45 <= x <= 60 mol%) were prepared by using the melt quenching method 1000 degrees C. The thermal stability of theses glasses increases with the substitution of Bi2O3 with PbO. The ionic conductivity of all compositions have been measured over a wide temperature (200-500 degrees C) and frequency range (1-106 Hz). The ionic conductivity data below and above T-g follows Arrhenius and Vogel-Tamman-Fulcher (VTF) relationship, respectively. The activation energies are estimated and discussed. The dependence in frequency of AC conductivity is found to obey Jonscher's relation. (C) 2015 Elsevier Ltd. All rights reserved.