Composition-dependent flotation kinetic models with distributed flotation rate constants for predicting the flotation response of the various components of coal have been available for quite some time. However, the full potential of these models have not been realised because the floatability distribution of particles, a key requirement for the utilisation of the models, has not been readily accessible experimentally to allow the validation of these models. A new approach has been developed that allows the coal flotation feed to be fractionated into particles classes of size and composition using a microscopic characterisation tool called Coal Grain Analysis. Previous work had determined the contact angles of discrete coal maceral groups and associated minerals. Combining this information with the particle composition data from the Coal Grain Analysis methodology provides a pathway for estimating the contact angles of heterogeneous coal particles via Cassie's Equation. The approach provides a unique opportunity to estimate the flotation rate constants for the different particle classes. (C) 2014 Elsevier Ltd. All rights reserved.