화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals, Vol.376, 283-288, 2002
New one-dimensional chain compounds of [M (pdz) Cl-2](n)(M=Cu(II), Fe(II), Mn(II); pdz = pyridazine and their magnetic properties
Three novel one-diniensional coordination polymers with pyridazine (pdz), [M (pdz) Cl-2]n (M = Cu (II) (1), Fe (II) (2), Mn (II) (3)), were synthesized and characterized. All the compounds have one-dimensional zigzag chain structures. The copper ion in compound 1 has a planer coordination sphere with two bridging pdz ligands and two Cl-anions, while the metal ions in the other compounds have a distorted octahedral environment with pdz and Cl- groups both acting as bridges. The magnetic data of these compounds show antiferromagnetic interaction between the magnetic centers within the chains.