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Petroleum Chemistry, Vol.55, No.7, 503-521, 2015
Kinetic models of methanol and dimethyl ether conversion to olefins over zeolite catalysts (Review)
The review summarizes various approaches to the description of the olefins synthesis kinetics from methanol/dimethyl ether for two types of zeolite catalyst, ZSM-5 and SAPO-34. It has been shown that along with phenomenological models, microkinetic models derived with taking account of the detailed reaction mechanism and quantum-chemical calculations based on the single-event concept of the reaction rate and the transition state theory are being widely used now. Both power laws and the Hougen-Watson equations are proposed to describe the rates of elementary steps.
Keywords:kinetics of ethylene and propylene synthesis;simulation/modelling;methanol;dimethyl ether;MTO process;ZSM-5 and SAPO-34 zeolite catalysts