Polymer Engineering and Science, Vol.55, No.6, 1237-1245, 2015
Residence time distributions in a co-kneader: A chemical engineering approach
In this article, we have studied the residence time distributions (RTD) in a modular co-kneader. Several papers have already addressed the co-kneader modeling and operating mode but there is still a lack of experimental data on RTD. To investigate the RTD, we have used a colored tracer dispersed in polypropylene (PP) that was injected in the flow during the compounding of neat PP. The effect of operating parameters such as temperature, feed rate, and screw configuration was investigated, focusing on the influence of mixing and conveying elements in a zone where the polymer is molten. As can be expected, results on various screw configurations show that increasing the number of kneading elements makes the RTD longer. More interestingly, for a defined set of elements, their position does not change the experimental RTD. A chemical engineering approach was used to model the RTD, with an equation derived from a cascade of continuous stirred tank reactors. The model allows to retrieve an elementary RTD for each section of a defined type of elements and to propose a law for their combination in good agreement with experiments. POLYM. ENG. SCI., 55:1237-1245, 2015. (c) 2015 Society of Plastics Engineers