화학공학소재연구정보센터
Przemysl Chemiczny, Vol.94, No.11, 1945-1948, 2015
The effect of mixing the supplying and receiving phases on transport of zinc(II) through polymer inclusion membranes
Zn cations were transported through polymer inclusion membrane in an app. consisting of 2 interconnected glass vessels, sepd. with a 17.8 mm thick membrane made of cellulose triacetate, 1-decyl-1,2,4-triazole and (BuO)(3)PO4. Each vessel was equipped with connector pipes to introduce a mech. stirrer and a sampler. Optionally, the app. was placed in an ultrasound bath (160 W, 40 kHz). In one of the vessels, the supply phase (1 mol/L) of an aq. soln. of ZnCl2 was placed, and the const. Cl (2 mol/L) concn. was maintained by addn. of NaCl. The mech., ultrasound or mech. supported with ultrasounds mixing was carried out at 20-60 degrees C. The Zn concn. in the receiving phase was detd. each 1 h by titration. The increase of the process temp. from 20 degrees C to 60 degrees C resulted in an increase of Zn recovery from 27.35% to 48.54% for the mech. mixing, from 29.87% to 58.14% for ultrasound mixing, and from 47.02% to 99.90% for ultrasound - supported mech. stirring.