화학공학소재연구정보센터
Solar Energy Materials and Solar Cells, Vol.141, 39-48, 2015
Comparing the Luttinger-Kohn-Pikus-Bir and the Empiric K . P Hamiltonians in quantum dot intermediate band solar cells manufactured in zincblende semiconductors
The calculation of the energy spectrum and absorption coefficients of quantum dot nanostructured intermediate band solar cells using the Empiric K . P Hamiltonian method and its agreement with experimental data are summarized. The well established Luttinger Kohn Hamiltonian modified by Pikus and Bir for strained material, such as quantum dot arrays, is presented using a simplified strain field that allows for square band offsets. The energy spectrum and absorption coefficients are calculated with this new Hamiltonian. With the approximations made the energy spectrum results to be exactly the same but the absorption coefficient fits experiments less accurately. The computer time using the latter Hamiltonian is much longer than the former one. (C) 2015 Elsevier B.V. All rights reserved.