화학공학소재연구정보센터
Thermochimica Acta, Vol.608, 40-48, 2015
Thermodynamic properties of cyclohexanamines: Experimental and theoretical study
Vapor pressures of cyclohexanamine, N-methyl-cyclohexanamine, N,N-dimethyl-cyclohexanamine, and N-cyclohexyl-cyclohexanamine were measured using the transpiration method. Molar enthalpies of vaporization of cyclohexanamine derivatives were derived from vapor pressure temperature dependences. Thermodynamic data on cyclohexanamine derivatives available in the literature were collected and treated uniformly. Consistency of the experimental data was proved with a group- contribution method and quantum-chemical calculations. Evaluated vaporization and formation enthalpies of cyclohexanamine derivatives were recommended for practical thermochemical calculations. (C) 2015 Elsevier B.V. All rights reserved.