화학공학소재연구정보센터
Thermochimica Acta, Vol.609, 31-35, 2015
Investigation of not fully stable fluids by the method of controlled pulse heating. 2. Short-term thermal stability of polymethyl metacrylate
The short-time thermal stability of glassy PMMA (polymethyl metacrylate) under conditions of high-power local heating has been studied experimentally. For this purpose, a peculiar procedure in the framework of the method of controlled pulse heating of implantable probe has been developed. The procedure is based on combining the thermal shock and monitoring heating functions with characteristic pulse lengths of the order of 1 mu s and 1 ms, respectively. The value of the characteristic probe temperature T-pk(*) was determined, a reproduction of which in a series of measurements under identical parameters of heating function resulted in irreversible changes in the thermal resistance of a polymeric sample. The depth of penetration into the region of thermal instability of polymer (T-pk(*) - T-d), where T-d is the onset temperature of thermal decomposition in quasi-static process, attains a few hundreds of degrees. (C) 2015 Elsevier B.V. All rights reserved.