화학공학소재연구정보센터
Thermochimica Acta, Vol.617, 200-207, 2015
Experimental evidence for two distinct deeply supercooled liquid states of water - Response to "Comment on Water's second glass transition", by GP Johari, Thermochim. Acta (2015)
Recently, our earlier data which led us to conclude that deeply supercooled water displays a second glass transition (Amann-Winkel et al., 2013) was reinterpreted (johad, 2015). In particular, the increase in heat capacity observed for high-density amorphous ice (HDA) samples at 116K was reinterpreted to indicate sub-T-g features of low-density amorphous ice's (LDA's) glass transition. We reply to the criticism in detail and report an experiment triggered by the comment on our work This experiment unequivocally confirms our original interpretation of the observations and reinforces the case for water's second glass transition, its polyamorphism, and the observation of two distinct ultraviscous states of water differing by about 25% in density. (C) 2015 Elsevier B.V. All rights reserved.