화학공학소재연구정보센터
Thin Solid Films, Vol.599, 104-112, 2016
Visualization and classification of epitaxial alignment at hetero-phase boundaries
We use the concept of a Map of Interfacial Periodicity to visualize and classify the periodicity at hetero-phase boundaries. Periodicity in the plane of the interface is a necessary condition to achieve an optimized bonding arrangement across the interface. A periodic boundary planemay be achieved by plane matching, i.e., a 2D match of crystal planes within the plane of the interface, or plane alignment, i.e., matching of lattice planes that are aligned across the interface. The latter mechanism results in axiotaxy and aligned epitaxy and improves robustness for the 'matching' nature of the interface with respect to perturbations in grain orientation or interfacial roughness. Examples are presented for different types of epitaxial interfaces between tetragonal alpha-FeSi2 or orthorhombic NiSi and Si(001), two systems that are known to exhibit both axiotaxial and epitaxial texture components. (C) 2015 Elsevier B.V. All rights reserved.