The peculiarities of charge flow mechanism in polymer films on the PEPC base with organic dyes of various ionic ability were investigated. The electroconductivity was established to depend oil dye nature, their ionic ability and content in polymer media. The approximation of the current-voltage characteristics as exponential function was presented and the activation mechanism of charge flow in investigated structures was established. The activation energy of various system was estimated end established to depend oil the dye concentration in PEPC. The self-organization as penta- and hexagons and. aggregation in investigated structures obtained.