Molecular Crystals and Liquid Crystals, Vol.429, 181-181, 2005
H-2-NMR of the induced chiral phases of acrylate-metacrylate liquid crystalline copolymers
It is shown that the addition of 2 to 6 wt.% of a chiral dopant (CD) to a series of nematic copolymers (Pn) induces blue and cholesteric mesophases. The mesomorphic behaviour of various CD + Pn mixtures is investigated by polarized optical microscopy and the phase transition. temperatures are determined by DSC measurements. Deuterium NMR spectra are recorded as a function of temperature within the mesophases and the spectral line shapes characteristic of different local orientational order parameters and orientational ordering processes of molecules in a magnetic field are observed depending on temperature, heating or cooling process, chiral dopant concentration, copolymer composition, and magnetic field strength.