The compounds from the fluorinated nF6B (n = 1,2,3,4,5,6,7) homologous series were investigated by means of optical, electrooptical, refractometrical, dielectric, densytometric, X-ray and IR spectroscopy methods. For some compounds being a subject of investigations a computer simulation of molecular properties were done. In our opinion high value of optical tilt 0(o) angle in comparison with a tilt angle obtained from X-ray measurements can be interpreted in terms of de Vries model of SmA(*) phases as well as of dimers creation process.