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Molecular Crystals and Liquid Crystals, Vol.453, 1-13, 2006
New generation of holographic gratings based on polymer-LC composites: POLICRYPS and POLIPHEM
Soft materials exhibit very attractive mechanical, optical, and electro-optical properties and easy processing techniques. Combined with holographic techniques, they can be patterned quite easily creating many unique structures. We present here few examples, of electrically-switchable passive opto-electronic components based on composite materials obtained from initial mixtures of photocurable monomers and liquid crystalline materials. Holographic exposure results in volume gratings consisting in alternate areas of photo-crosslinked polymer and phase separated LCs, respectively. We discuss the main features of this new generation of gratings and show how most of their performances can be enhanced with respect to other kinds of composite gratings, like H-PDLCs.
Keywords:holographic gratings;opto-electronic components;polymer-liquid crystal composites;soft matter