The synthesis and properties of a series of new glass-forming condensed aromatic amines are reported. The dependence of their thermal and optical propertiess oil their chemical structure is discussed. The ionization potentials of the synthesized aromatic amines treasured by the electron photoemission technique are 5.30-5.40eV. Hole drift mobilities of some derivatives molecularly dispersed in bisphenol Z polycarbonate exceed 10(-6) cm(2) V-1 s(-1) at high electric fields (10(6) V cm(-1)), at room temperature.