Molecular Crystals and Liquid Crystals, Vol.544, 112-118, 2011
Optical Director Reorientation in NLCs Doped with Light-Absorbing Codendrimers of Different Generations
The orientational optical nonlinearity induced in NLCs by light-absorbing carbosilane codendrimers with statistical distribution of terminal aliphatic and azobenzene fragments has been studied comparatively for different (from the second to the fourth) codendrimer generations. It was found that all the codendrimers induce the negative nonlinearity (director rotates away from the light field thus decreasing the refractive index of the extraordinary wave). The orientational response increases with the generation number. The optical bistability is manifested for NLCs doped with the codendrimers of the second and third generations.
Keywords:Dendrimers;light-induced Freedericksz transition;nematic liquid crystals;orientational nonlinearity