Molecular Crystals and Liquid Crystals, Vol.547, 91-96, 2011
Reviewing the Mechanisms That Affect the Critical Behaviour of Nematic Side-Chain and Main-Chain Elastomers
A review of the mechanisms that influence the critical behaviour of the nematic monodomain main-chain and side-chain liquid-crystalline elastomers is presented. The crosslinking density, the applied mechanical load and the temperature at which the second crosslinking step takes place are examples of such mechanisms. This knowledge is a powerful tool when the tuning of the critical behaviour and, thus, of the thermo-mechanical response of the elastomers is needed.