화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals, Vol.586, No.1, 76-81, 2013
Effects of the Modified TCO Sputtering Condition on ZnS/CIGS Solar Cell
The Cu(In,Ga)Se-2(CIGS) thin film solar cells were fabricated using ZnS buffer layer deposited by chemical bath deposition and ZnO/Al-doped ZnO transparent conducting layers deposited by magnetron sputtering with two different configurations of target-to-substrate angle and distance in order to evaluate the effect of plasma damage on device performance. The higher efficiency was obtained from the configuration of the substrate being far away from the target center than face-to-face configuration, suggesting that the excessive bombardment of high energy particles from the plasma on the film surface is responsible for the solar cell performance degradation. It is suggested that the improved open-circuit voltage is ascribed to the increased recombination barrier height.