Polymer-stabilized V-mode Ferroelectric Liquid Crystals (PSV-FLCs) are attractive for a next generation of LC display. However, in the rubbing technique which is conventionally used for LC molecular alignment, the rubbing scratches form on the alignment film surface, and then, the rubbing scratch pattern is clearly observed in the texture of FLC. Therefore, the high contrast ratio cannot be obtained due to the optical leakage. In this research, we introduce the photo-alignment technique to PSV-FLC. As a result, the optical leakage can be largely suppressed by the photo-alignment technique, and thus, the photo-alignment technique is effective to PSV-FLCs.