N-{[(4-bromophenyl) amino]carbonothioyl}benzamide was synthesized and characterized by IR, (1) H-and (13)C-NMR, mass spectrometry, and elemental analysis. The crystal structure was determined from single crystal X-ray diffraction data. It crystallizes in monoclinic space group P21/n with unit cell dimensions a = 13.822(3) angstrom, b = 5.927(2) angstrom, c = 16.642(3) angstrom, and beta = 103.963(3)degrees. There is a strong intramolecular hydrogen bond of the type N(-)HAO, with an HAO distance of 2.6129 (11) angstrom. The mass fragmentation pattern is also discussed.