Advanced Materials, Vol.27, No.33, 4871-4876, 2015
Probing Ferroelectric Domain Engineering in BiFeO3 Thin Films by Second Harmonic Generation
An optical probe of the ferroelectric domain distribution and manipulation in BiFeO3 thin films is reported using optical second harmonic generation. A unique relation between the domain distribution and its integral symmetry is established. The ferroelectric signature is even resolved when the film is covered by a top electrode. The effect of voltage-induced ferroelectric switching is imaged.
Keywords:BiFeO3;domains;ferroelectric;magnetoelectric;multiferroic;scanning probe microscopy;second harmonic generation