화학공학소재연구정보센터
AIChE Journal, Vol.61, No.4, 1447-1454, 2015
Moving Ion Fronts in Mixed Ionic-Electronic Conducting Polymer Films
The aim of this paper is to analyze moving front dynamics of ions and holes in a planar, mixed ionic-electronic conducting polymer film. As cations invade the film, holes evacuate; thus, an ionic current is converted to an electronic signal. Recent experiments show that the location of the advancing ion front increases as the square-root of time, a scaling typically associated with diffusive transport, which is surprising given the large driving voltages utilized. Ionic and electronic transport is modeled via the drift-diffusion equations. A similarity transformation reduces the governing partial differential equations to ordinary differential equations that are solved numerically. The similarity transformation elucidates the origin of the square-root-of-time front scaling. The similarity solution is then compared to the numerical solution of the full drift-diffusion equations, finding excellent agreement. When compared with experimental data, our model captures the front location; however, qualitative differences between the ion profiles are observed. (C) 2015 American Institute of Chemical Engineers