화학공학소재연구정보센터
Biomass & Bioenergy, Vol.86, 180-190, 2016
Changes in feedstock quality in willow chip piles created in winter from a commercial scale harvest
Storage and handling are important facets of biomass logistics because there are associated costs and biomass properties can change significantly as material proceeds through the supply chain. Thus, this aspect of biomass supply systems requires continued study. Shrub willow chips were harvested, and used to create six piles that each contained between 10 and 22 Mg (fresh biomass). Material was monitored for several months in temporary storage to assess changes in biomass quality (moisture, ash and energy content). Internal pile temperatures increased due to biological activity and conditions within a pile quickly differentiated based on location (shell, core, top, and side). Mean moisture content increased from 42 to 47% (mass fraction) between harvest and delivery of the chips, but ranged between 37 and over 60% over the next three months depending on pile location with the shell generally drier than the core. Mean ash content increased 1 to 2% points (mass fraction) between harvesting, reloading and delivery to the trial location, but became more variable during storage. Higher heating values (HHV) were stable between 18.6 and 19.0 MJ kg(-1) over the six months, but lower heating values (LHV) ranged between 8.6 and 11.7 MJ kg(-1) and mirrored changes in moisture content. There was minimal change in chip quality over two months, but quality became more variable over longer time periods. This period could be extended, and negative effects on chip quality could be mitigated, by improving storage methods, blending different types of chips, or employing pretreatments. (C) 2016 Elsevier Ltd. All rights reserved.