Chemistry Letters, Vol.44, No.9, 1257-1259, 2015
Designed Synthesis of Porphyrin-based Two-dimensional Covalent Organic Frameworks with Highly Ordered Structures
Porphyrins are representative functional pi-systems; synthesizing their highly ordered structures is an established goal in chemistry. Here, we report the designed synthesis of a series of porphyrin-based covalent organic frameworks with highly ordered structures through polycondensation. The porphyrinbased frameworks exhibited high crystallinity, high porosity, and extended pi-conjugation over the polyporphyrin sheets.