Journal of Crystal Growth, Vol.441, 107-116, 2016
Radial macrosegregation and dendrite clustering in directionally solidified Al-7Si and Al-19Cu alloys
Hypoeutectic Al-7 wt% Si and Al-19 wt% Cu alloys were directionally solidified upward in a Bridgman furnace through a range of constant growth speeds and thermal gradients. Though processing is thermosolutally stable, flow initiated by gravity-independent advection at, slightly leading, central dendrites moves rejected solute out ahead and across the advancing interface. Here any lagging dendrites are further suppressed which promotes a curved solid-liquid interface and the eventual dendrite "clustering" seen in transverse sections (dendrite "steepling" in longitudinal orientations) as well as extensive radial macrosegregation. Both aluminum alloys showed considerable macrosegregation at the low growth speeds (10 and 30 mu m s(-1)) but not at higher speed (72 mu m s(-1)). Distribution of the fraction eutectic constituent on transverse sections was determined in order to quantitatively describe radial macro segregation. The convective mechanisms leading to dendrite-steepling were elucidated with numerical simulations, and their results compared with the experimental observations. (C) 2016 Elsevier B.V. All rights reserved.
Keywords:Directional solidification;Computer simulation;Fluid flows;Segregation;Bridgman technique Aluminum alloys