Densities and surface tensions of binary mixtures of biodiesel, diesel, and n-butanol

Hongya Yue; Zhigang Liu

Korean Journal of Chemical Engineering, Vol.33, No.5, 1692-1697, May, 2016

DOI10.1007/s11814-015-0290-9 Export Citation

Densities and surface tensions of binary mixtures of biodiesel, diesel, and n-butanol

Hongya Yue^†, and Zhigang Liu

Key Laboratory of Thermo-Fluid Science and Engineering, Ministry of Education,, Xi’an Jiaotong University, Shaanxi Province 710049, P. R. China

E-mail:

Density and surface tension have been measured for mixtures of biodiesel+n-butanol, biodiesel+diesel, and diesel+n-butanol over the entire concentration range at 283.15 K and 293.15 K and atmospheric pressure, with the combined expanded uncertainties of 1.32 kg·m-3 and 1%, receptively. Densities were determined by a single-sinker densimeter; surface tensions were measured using the surface laser light scattering method. The experimental data showed that densities and surface tensions decreased as temperature increased. The excess surface tensions and excess densities were all negative, and further fitted to the Redlich-Kister equation.

Keywords:Surface Tension;Surface Laser Light Scattering Method;Biodiesel;Diesel;n-Butanol

[References]

Lujaji F, Bereczky A, Mbarawa M, Energy Fuels, 24, 4490 (2010)
Huang Z, Miao H, Zhou L, Jiang D, P. I. Mech. Eng. D-J. Aut., 214, 341 (2000)
Noboru M, Hideyuki O, Kohichi O, JASE Review, 19, 154 (1988)
Zhu L, Cheung CS, Zhang WG, Huang Z, Sci. Total Environ., 408, 914 (2010)
Zhang B, Fu WB, Gong JS, Fuel, 85(5-6), 778 (2006)
Alptekin E, Canakci M, Renew. Energy, 33(12), 2623 (2008)
Bahadur NP, Boocock DG, Konar SK, Energy Fuels, 9(2), 248 (1995)
Deng P, Huang R, Ma Y, Dai H, SAE Technical. Paper., 2013-01-2598 (2013).
Wang FK, Wu JT, Liu ZG, Energy Fuels, 20(6), 2471 (2006)
Nishio T, Nagasaka Y, Int. J. Thermophys., 16, 1087 (1995)
Ingrad KU, Fundamentals of Waves & Oscillations, Great Britain:the University Press, Cambridge, 478 (1988).
Ingard KU, Fundamentals of Waves & Oscillations, U.K. (1988).
An YY, Liu JF, Li QH, Optoelectronic Technology, Beijing (2002).
ISO, Guide to the Expression of Uncertainty in Measurement. International Organisation for Standardisation, Switzerland. 9-71 (1995).
Zhao GJ, Development of Surface Laser Light Scattering Apparatus for Liquid Viscosity and Surface Tension Measurement and Its Applications, Xi’an, Xi’an Jiao Tong University (2006).
Valles C, Perez E, Cardoso M, Dominguez M, Mainar AM, J. Chem. Eng. Data, 49(5), 1460 (2004)
Tahery R, Modarress H, Satherley J, J. Chem. Eng. Data, 51(3), 1039 (2006)
Wohlfarth C, Wohlfarth B, Surface Tension of Pure Liquids and Binary Liquid Mixtures, Volume 16, Springer-Verlag (1997).
Giner B, Villares A, Martin S, Artigas H, Lafuente C, J. Chem. Eng. Data, 52(5), 1904 (2007)
Pan CR, Ke QF, Ouyang GF, Zhen XH, Yang YY, Huang ZQ, J. Chem. Eng. Data, 49(6), 1839 (2004)
Vijande J, Pineiro MM, Garcia J, Valencia JL, Legido JL, J. Chem. Eng. Data, 51(5), 1778 (2006)
Redlich O, Kister A, Ind. Eng. Chem., 40, 345 (1948)
Mohammad AA, Alkhaldi KHAE, AlTuwaim MS, Al-Jimaz AS, J. Chem. Thermodyn., 56, 106 (2013)
Tsierkezos NG, Filippou AC, J. Chem. Thermodyn., 38(8), 952 (2006)
Mesquita FMR, Feitosa FX, Santiago RS, de Sant'Ana HB, J. Chem. Eng. Data, 56(1), 153 (2011)

[1] Lujaji F, Bereczky A, Mbarawa M, Energy Fuels, 24, 4490 (2010)

[2] Huang Z, Miao H, Zhou L, Jiang D, P. I. Mech. Eng. D-J. Aut., 214, 341 (2000)

[3] Noboru M, Hideyuki O, Kohichi O, JASE Review, 19, 154 (1988)

[4] Zhu L, Cheung CS, Zhang WG, Huang Z, Sci. Total Environ., 408, 914 (2010)

[5] Zhang B, Fu WB, Gong JS, Fuel, 85(5-6), 778 (2006)

[6] Alptekin E, Canakci M, Renew. Energy, 33(12), 2623 (2008)

[7] Bahadur NP, Boocock DG, Konar SK, Energy Fuels, 9(2), 248 (1995)

[8] Deng P, Huang R, Ma Y, Dai H, SAE Technical. Paper., 2013-01-2598 (2013).

[9] Wang FK, Wu JT, Liu ZG, Energy Fuels, 20(6), 2471 (2006)

[10] Nishio T, Nagasaka Y, Int. J. Thermophys., 16, 1087 (1995)

[11] Ingrad KU, Fundamentals of Waves & Oscillations, Great Britain:the University Press, Cambridge, 478 (1988).

[12] Ingard KU, Fundamentals of Waves & Oscillations, U.K. (1988).

[13] An YY, Liu JF, Li QH, Optoelectronic Technology, Beijing (2002).

[14] ISO, Guide to the Expression of Uncertainty in Measurement. International Organisation for Standardisation, Switzerland. 9-71 (1995).

[15] Zhao GJ, Development of Surface Laser Light Scattering Apparatus for Liquid Viscosity and Surface Tension Measurement and Its Applications, Xi’an, Xi’an Jiao Tong University (2006).

[16] Valles C, Perez E, Cardoso M, Dominguez M, Mainar AM, J. Chem. Eng. Data, 49(5), 1460 (2004)

[17] Tahery R, Modarress H, Satherley J, J. Chem. Eng. Data, 51(3), 1039 (2006)

[18] Wohlfarth C, Wohlfarth B, Surface Tension of Pure Liquids and Binary Liquid Mixtures, Volume 16, Springer-Verlag (1997).

[19] Giner B, Villares A, Martin S, Artigas H, Lafuente C, J. Chem. Eng. Data, 52(5), 1904 (2007)

[20] Pan CR, Ke QF, Ouyang GF, Zhen XH, Yang YY, Huang ZQ, J. Chem. Eng. Data, 49(6), 1839 (2004)

[21] Vijande J, Pineiro MM, Garcia J, Valencia JL, Legido JL, J. Chem. Eng. Data, 51(5), 1778 (2006)

[22] Redlich O, Kister A, Ind. Eng. Chem., 40, 345 (1948)

[23] Mohammad AA, Alkhaldi KHAE, AlTuwaim MS, Al-Jimaz AS, J. Chem. Thermodyn., 56, 106 (2013)

[24] Tsierkezos NG, Filippou AC, J. Chem. Thermodyn., 38(8), 952 (2006)

[25] Mesquita FMR, Feitosa FX, Santiago RS, de Sant'Ana HB, J. Chem. Eng. Data, 56(1), 153 (2011)