Anticorrosive properties of olive oil polyurethanamide/ZnO biocomposite coatings

Manawwer Alam; Naser Mohammed Alandis; Eram Sharmin; Fahmina Zafar; Mohammad Asif Alam

Korean Journal of Chemical Engineering, Vol.33, No.5, 1736-1742, May, 2016

DOI10.1007/s11814-016-0009-6 Export Citation

Anticorrosive properties of olive oil polyurethanamide/ZnO biocomposite coatings

Manawwer Alam^†, Naser Mohammed Alandis¹, Eram Sharmin², Fahmina Zafar³, and Mohammad Asif Alam⁴

Research Centre-College of Science, King Saud University, P. O. Box 2455, Riyadh 11451, Saudi Arabia
¹Department of Chemistry, College of Science, King Saud University, P. O. Box 2455, Riyadh 11451, Saudi Arabia
²Department of Pharmaceutical Chemistry, College of Pharmacy, Umm Al-Qura University, P. O. Box 715, Makkah Al-Mukarramah, 21955, Saudi Arabia
³Inorganic Materials Research Laboratory, Department of Chemistry, Jamia Millia Islamia, New Delhi 110 025, India
⁴Advanced Manufacturing Institute, Center of Excellence in Engineering Materials, King Saud University, P. O. Box 800, Riyadh-11421, Saudi Arabia

E-mail:

Olive oil based polyurethanamide/ZnO biocomposites were prepared by energy efficient microwave irradiation technique. The biocomposites showed good coating properties: scratch resistance, impact resistance, adhesion and flexibility retention. The corrosion studies carried out by potentiodynamic polarization measurements exhibit inhibition efficiency of 99.99% in 5% NaCl, 99.99% in 3.5% HCl, and 99.94% tap water, respectively. The overall approach is significant as it focuses on the utilization of vegetable oil, a sustainable material, polyurethanamide, synthesized through an energy efficient technique, at lower temperature, in lower reaction time, promoting value addition through simple chemistry. The coatings provide corrosion protection by barrier action.

Keywords:Olive Oil;Polyurethane;Coatings;ZnO;Potentiodynamic

[References]

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Alam M, Akram D, Sharmin E, Zafar F, Ahmad S, Arab. J. Chem., 7, 469 (2014)
Sharmin E, Zafar F, Akram D, Alam M, Ahmad S, Ind. Crop. Prod., 76, 215 (2015)
Dutta S, Karak N, Prog. Org. Coat., 53, 147 (2005)
Yadav S, Zafar F, Hasnat A, Ahmad S, Prog. Org. Coat., 64, 27 (2009)
Kashif M, Zafar F, Ahmad S, J. Appl. Polym. Sci., 117(3), 1245 (2010)
Kashif M, Shamin E, Zafar F, Ahmad S, J. Am. Oil Chem. Soc., 88, 1989 (2011)
Zafar F, Kashif M, Sharmin E, Ahmad S, Macromol. Symp., 290, 79 (2010)
Ahmad S, Zafar F, Sharmin E, Garg N, Kashif M, Prog. Org. Coat., 73, 112 (2012)
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Sharmin E, Rehman O, Zafar F, Akram D, Alam M, Ahmad S, RSC Adv., 5, 47928 (2015)
Dhoke SK, Khanna AS, Corrosion Sci., 51, 6 (2009)
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Hoogenboom R, Schubert US, Macromol. Rapid Commun., 28(4), 368 (2007)
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[1] Sharma V, Kundu PP, Prog. Polym. Sci, 33, 1199 (2008)

[2] Guner FS, Yagci Y, Erciyes AT, Prog. Polym. Sci., 31, 633 (2006)

[3] Alam M, Akram D, Sharmin E, Zafar F, Ahmad S, Arab. J. Chem., 7, 469 (2014)

[4] Sharmin E, Zafar F, Akram D, Alam M, Ahmad S, Ind. Crop. Prod., 76, 215 (2015)

[5] Dutta S, Karak N, Prog. Org. Coat., 53, 147 (2005)

[6] Yadav S, Zafar F, Hasnat A, Ahmad S, Prog. Org. Coat., 64, 27 (2009)

[7] Kashif M, Zafar F, Ahmad S, J. Appl. Polym. Sci., 117(3), 1245 (2010)

[8] Kashif M, Shamin E, Zafar F, Ahmad S, J. Am. Oil Chem. Soc., 88, 1989 (2011)

[9] Zafar F, Kashif M, Sharmin E, Ahmad S, Macromol. Symp., 290, 79 (2010)

[10] Ahmad S, Zafar F, Sharmin E, Garg N, Kashif M, Prog. Org. Coat., 73, 112 (2012)

[11] Zafar F, Mir MH, Kashif M, Sharmin E, Ahmad S, J. Inorg. Organomet. Polym. Mater., 21, 61 (2011)

[12] Zafar F, Zafar H, Sharmin E, J. Appl. Polym. Sci., 131, 40278 (2014)

[13] Sharmin E, Rehman O, Zafar F, Akram D, Alam M, Ahmad S, RSC Adv., 5, 47928 (2015)

[14] Dhoke SK, Khanna AS, Corrosion Sci., 51, 6 (2009)

[15] Sari MG, Ramezanzadeh B, Shahbazi M, Pakdel AS, Corrosion Sci., 92, 162 (2015)

[16] Kornmann X, Berglund LA, Sterte J, Polym. Eng. Sci., 38(8), 1351 (1998)

[17] Farbod A, Parvinzadeh GM, Ali S, Amir K, Superlattices Microstruct., 52, 50 (2012)

[18] Golru SS, Attar MM, Ramezanzadeh B, Prog. Org. Coat., 77, 1391 (2014)

[19] Mallakpour S, Dinari M, Prog. Org. Coat., 75, 173 (2012)

[20] Shaik MR, Alam M, Alandis NM, J. Nanomater, Article ID 745217 (2015)., 2015 (2015)

[21] Gashti MP, Almasian A, Gashti MP, Sens. Actuators A-Phys., 187, 1 (2012)

[22] Parvinzadeh M, Eslami S, Res. Chem. Intermed., 37, 771 (2011)

[23] Joy LK, Sooraj V, Sajeev US, Nair SS, Narayanan TN, Sethulakshmi N, Ajayan PM, Anantharaman MR, Appl. Phys. Lett., 104, 121603 (2014)

[24] Dey A, Panja S, Sikder AK, Chattopadhyay S, RSC Adv., 5, 10358 (2015)

[25] Gashti MP, Almasian A, Composites Part B, 45, 282 (2013)

[26] Siyanbola TO, Sasidhar K, Anjaneyulu B, Kumar KP, Rao BVSK, Narayan R, Olaofe O, Akintayo ET, Raju KVSN, J. Mater. Sci., 48(23), 8215 (2013)

[27] Alam M, Alandis NM, Prog. Org. Coat., 75, 527 (2012)

[28] Alam M, Alandis NM, Ansari AA, Shaik MR, J. Nanomater, Article ID 157810, 2013 (2013)

[29] Hoogenboom R, Schubert US, Macromol. Rapid Commun., 28(4), 368 (2007)

[30] Alam M, Sharmin E, Ashraf SM, Ahmad S, Prog. Org. Coat., 50, 224 (2004)

[31] Meshram PD, Puri RG, Patil AL, Gite VV, J. Coat. Technol. Res., 10, 331 (2013)