화학공학소재연구정보센터
Solar Energy, Vol.129, 207-216, 2016
Electroanalytical investigation of the losses during interfacial charge transport in dye-sensitized solar cell
In the present article, the direct current and alternating current characterization techniques are employed to investigate the losses during interfacial charge transport in dye-sensitized solar cell (area: 3.78 cm(2)) having a power conversion efficiency of 4.32%. The analysis of current voltage characteristics depicts that the loss in photocurrent density is about 1-1.5% at low forward bias, similar to 8% at knee voltage and similar to 79% at open circuit voltage. The electrochemical impedance spectroscopy measurement leads to the direct determination of recombination resistance, chemical capacitance, charge transport resistance and double layer capacitance. The current voltage characteristics obtained from the impedance parameters allows separating the contributions of different resistive processes on the overall conversion efficiency. The experimental results along with the analytical model provide an insight into the electric power loss mechanism, which is useful for analyzing performance of other upcoming devices with a similar working mechanism like perovskite sensitized solar cells. (C) 2016 Elsevier Ltd. All rights reserved.